CHARACTERISTICS OF SHUNGITE ROCK FOR USE IN ALLOY PRODUCTION PROCESSES
DOI:
https://doi.org/10.34185/1991-7848.itmm.2025.01.018Keywords:
shungite, silica, carbon, reduction, thermodynamics of the Si-C-O system.Abstract
The natural composite material shungite, which has a complex mineral composition, is considered. One of the main components of the mineral component of shungite rocks of different groups is silica. Shungite carbon is evenly distributed in a silicate framework of finely dispersed quartz crystals. Shungite can be used as a raw material for smelting silicomanganese and ferrosilicon. The content of highly active carbon and silica in a ratio close to the stoichiometric one for the reaction of silicon reduction by carbon contributes to almost complete reduction of silicon from this material. Assuming that the shungite rock is a Si-C-O system, thermodynamic calculations of the composition of the equilibrium gas phase for the temperature range of 1300-2300 K were performed. The results of calculations of the equilibrium composition of the gas phase in the Si-C-O system at P = 1 atm showed that the minimum temperature of the formation of condensed silicon carbide (β-SiC) is 1756 K.
References
Snizhko O.M., Lashko S.P., Yatsenko V.G. On shungites and shungite mineral raw materials of Ukraine. // Collection of scientific papers of the Institute of Environmental Geochemistry. - 2005. - Issue 11. - P. 80–88. [in Ukrainian].
New data on high-carbon shungite-like rocks of the Mlynkovsky site (Krivoy Rog-Kremenchug zone, Ukrainian shield) / Yatsenko V.G., Zaborovskaya L.P., Pokalyuk V.V., Lashko S.P., Zaborovsky V.S., Lyzhachenko N.N. // Geochemistry of technogenesis. - No. 2. - 2019. - P. 33-45. https://doi.org/10.15407/geotech2019.30.033
Ignatov I., Mosin O. Composition and structural properties of fullerene analogous mineral shungite. Mathematical model of interaction of shungite with water molecules. Adv. Phys. Theor. Appl. 2014, 28, 10–21.
Geospatial data on the distribution of silicon and aluminum in the thickness of shungite rocks of the Mlynkovskii area (Ukrainian Shield) / Lashko S. P., Yatsenko V. G., Pokalyuk V. V., Zaborovskaya L. P. // Geoinformatics: Theoretical and Applied Aspects 2020. 11-14 May 2020, Kyiv, Ukraine. Volume 2020, p.1-5. https://doi.org/10.3997/2214-4609.2020geo064
Removal of Impurities from Shungite Via a Combination of Physical and Chemical Treatments. / Fujita T., Aoki T., Ponou J. et al. // Minerals 2021, 11, 245.
Preparation of Activated Shungite and Characterization of Its Chemical Composition and Adsorption Properties. / Kazankapova M.K., Nauryzbaev M.K., Efremov S.A. et al. // Solid Fuel Chem. 2019, 53, 241–247.
Ferrari A.C., Robertson J. Interpretation of Raman spectra of disorderes and amorphous carbon // Physical review B. 2000. Vol. 61, No 20. Р. 14095–14107. DOI:10.1103/PhysRevB.61.14095
Application of TG-FTIR to study SO2 evolved during the thermal decomposition of coal-derived pyrite. / Cheng H., Liu Q., Huang M., Zhang S., Frost R.L. // Thermochimia Acta. - 2013. - Vol. 555. - P. 1–6. https://doi.org/10.1016/j.tca.2012.12.025
Microwave heating characteristics of graphite based powder mixtures. / Chandrasekaran S., Basak T., Srinivasan R. // International Communications in Heat and Mass Transfer. 2013, 48, 22–27. http://dx.doi.org/10.1016/j.icheatmasstransfer.2013.09.008