ANALYSIS OF THE CONDITION OF THE THERMAL RESERVE ZONE OF THE BLAST FURNACE WHEN USING COAL COMPOSITIONS IN THE CHARGE

Authors

  • A. A.Vanyukov
  • L.V. Kamkina
  • V.P. Ivashchenko
  • Ya.V. Myanovska
  • P.O. Sazonov

DOI:

https://doi.org/10.34185/

Keywords:

blast furnace, ore-coal composite, recovery of iron oxides, carbon gasification, thermograms in a blast furnace, thermal reserve zone of a blast furnace, cohesion zone.

Abstract

The emergence and existence of zones in the blast furnace due to the laws of heat exchange are considered. In the middle zone of the blast furnace, the temperature of the outgoing gas stream remains relatively constant and no chemical processes occur in it. This is the "thermal reserve zone", the upper part of this zone - the "chemical reserve zone" is represented by wustite, which is not restored. The reserve of this zone is the formation of a gas phase. When additives are added to the charge of ore-coal compositions, iron oxides are reduced (t=1000 °C) by the reaction Fe2O3+C=Fe3O4+CO2 and carbon gasification СО2+С=2СО (Boudoir reaction). The resulting gas phase (CO) intensively reduces iron oxides. Composites for blast furnace smelting are produced from a mixture of blast furnace slurries with cement additives. The mixture is processed into coal pellets or briquettes. Blast furnace smelting at metallurgical plants in Ukraine, South Korea, and Japan has shown that the use of ore-coal composites is an effective additive to the charge of blast furnace smelting to reduce coke consumption. The coal-coal composite effect is based on the theory of "Coupling Phenomenon" between carbon and iron-containing materials in the composite pellet. Their interaction takes place, as research has shown, at temperatures of 250-420°C in a CO atmosphere. Taking into account the Boudoir reaction, the temperature in the thermal reserve zone of the blast furnace decreases by 80-200°C. Thus, in the chemical reserve zone, the recovery of wustite does not occur at 1000°C, but at 920-800°C, and it moves closer to the zones of iron and slag formation. The article analyzes thermograms in a blast furnace taking into account red coal deposits. Chemically, the reserve zone is located in the middle of the mine (from the slag surface) 11.2 m. With an increase in the consumption of composite in the charge (30%), the position of the reserve zone decreases from 11.2 to 6.2 m. The width between the thermograms of 1200°C - 1400°C is a characteristic zone of cohesion, with an increase in the consumption of the composite, it decreases from 2.1 m t (without loading the composite) to 0.9 m with a consumption of the composite of 30%.

References

M.A. Pavlov. Metalurhiia chavunu. M. 1949 r.-628 s.

B.I, Kytaiev. Teploobmin u shakhtnykh pechakh, M., Metallurhyzdat, 1945 r.

B.I. Kytaiev, Skhema teploobminu v domennii pechi i pidhotovka rud do plavky //

Stal - 1944 - №7-8.

B.I.Kytaiev, Yu.H. Yaroshenko i B.L. Lazariev. Teploobmin u domennii pechi //M. Metalurhiia ,1966 -355 s.

D.H. Pisi, V.H. Davenport. Domennyi protses - Teoriia i praktyka- M. Metalurhiia. 1984 - s. 27.

I.H. Tovarovskyi, V.P. Lialiuk. Evoliutsiia domennoi plavky. Dnipropetrovsk, Porohy 2001. S. 61-69, 424s.

S.V. Shavrin, A.V. Chentsov. Vybir rivnian dlia analizu teploobminu v domennykh pechakh // Forsuvannia domennoi plavky / pratsi naukovykh konferentsii z teorii vyp. metalurhii chavunu. metalurhii. metalurhvydav. 1963 - s169-172.

A.N. Ramm. Suchasnyi domennyi protses M. / Metalurhiia - 1980. 304 s.

Vvedennia v suchasnyi domennyi protses. Heerdes

M., Toksopeus Kh. 2004. ISBN: 572379871318

Doslidzhennia vzaiemozviazku rozpodilu temperatury ta khimichnoho skladu hazovoho potoku za radiusom domennoi pechi / V.I. Bolshakov, V.V. Lebed // Fundamentalni ta prykladni problemy chornoi metalurhii. Lebid // Fundamentalni ta prykladni problemy chornoi metalurhii: Zb. nauk. tr. - Dnipropetrovsk.: IChM NAN Ukrainy, 2006. Vyp. 13. S.27-35. http://dspace.nbuv.gov.ua/handle/123456789/21625

M.I. Krasavtsev, V.F, Kuzmenko. Doslidzhennia teploobminnykh protsesiv u shakhti domennoi pechi obiemom 2300 m3// Metalurhiia chavunu: Zbirnyk prats. Vypusk 18. DonNDICherMet. M.: Metalurhiia, 1970. S. 91-102.

M.M. Babarykin. Vplyv vidnovliuvalnykh protsesiv na teploobmin u domennii pechi // Stal. 1981 №3. S.5-9.

Treatise on Process Metallurgy. Volume 3: Industrial Processes. 2014, Pages 2-88. Chapter 1.1 – Ironmaking. Yongxiang Yang, Kalevi Raipala, Lauri Holappa. https://doi.org/10.1016/B978-0-08-096988-6.00017-1

STACHURA, R. Determination of the reserve zone localization in the working area of blast furnace. HutnikWiadomoci Hutnicze vol. 80, No. 11 2013 pp.752-756.

Hirokazu Yokoyama, Kenichi Higuchi, Takashi Ito, Akiyoshi Oshio. Decrease in Carbon Consumption of a Commercial Blast Furnace by Using Carbon Composite Iron Ore. ISIJ International, Vol. 52 (2012), No. 11, pp. 2000–2006. http://dx.doi.org/10.2355/isijinternational.52.2000

K. Higuchi, K. Kunitomo and S. Nomura. Reaction Behaviors of Various Agglomerates in Reducing the Temperature of the Thermal Reserve Zone of the Blast Furnace : ISIJ International, V 60, (2020),№11, pp.2366-2375.

DOI:10.2355/isijinternational.ISIJINT-2020-115

D.A. Kovalov, B.P. Krykunov, A.A. Vaniukov. Efektyvnist zastosuvannia hranulovanoho vuhletsevmisnoho zalizofliusu v domennii plavtsi. /VAT «Chermetinformatsiia». Biulliuten «Chorna metalurhiia» - 2012 №7 -s.49-54.

Kovalov D. A., Vaniukova N. D., Vaniukov A. A. Vyrobnytstvo i vykorystannia samovidnovliuvalnykh okatyshiv u domennii plavtsi iz zastosuvanniam pylovuhilnoho palyva // Metalurhiina i hirnychorudna promyslovist. - 2013 - №1 - S. 13-15.

Kovalov D.A., Vaniukov A.A., Krykunov B.P. Vyrobnytstvo vysokoosnovnykh samovidnovliuvalnykh okatyshiv na tsementnii zviaztsi ta domenna plavka z yikh vykorystanniam. // «Metalurhiina ta hirnychorudna promyslovist». - 2014. -№5. - S. 2-4.

ISIJ International. Volume 41 (2001). Issue 8. Reaction Behavior of Facing Pair between Hematite and Graphite: A Coupling Phenomenon of Reduction and Gasification. Yoshiaki Kashiwaya, Motomichi Kanbe, Kuniyoshi Ishii. JOURNAL FREE ACCESS. 2001. Volume 41. Issue 8. Pages 818-826. https://doi.org/10.2355/isijinternational.41.818

A. Kasai and Y. Matsui. Lowering of thermal Reserve Zone Temperature in Blast Furnace by Adjoining Carbonaceous Material and Irone Ore. ISIJ International, vol 44 (2004), №12, pp. 2073-2078. https://doi.org/10.2355/isijinternational.44.2073

A Numerical Study on the State of the Blast Furnace Thermal Reserve Zone under Different Starting Temperatures of Coke Solution Loss Reaction. Fanchao Meng, Lei Shao, Wenjie Ni, Zongshu Zou. 2022. https://doi.org/10.1002/srin.202100823

ISIJ International/Volume 52 (2012) Issue 11. Decrease in Carbon Consumption of a Commercial Blast Furnace by Using Carbon Composite Iron Ore. Hirokazu Yokoyama, Kenichi Higuchi, Takashi Ito, Akiyoshi Oshio. JOURNAL OPEN ACCESS. Pages 2000-2006

DOI https://doi.org/10.2355/isijinternational.52.2000

ISIJ International/Volume 44 (2004) Issue 12. Lowering of Thermal Reserve Zone Temperature in Blast Furnace by Adjoining Carbonaceous Material and Iron Ore. Akito Kasai, Yoshiyuki Matsui. JOURNAL FREE ACCESS. Pages 2073-2078

DOI https://doi.org/10.2355/isijinternational.44.2073

Downloads

Published

2024-05-24